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光催化 2

2 1

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Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 265-270 doi: 10.1007/s11783-009-0019-2

摘要： CoO-SnO hybrid oxides were prepared by the coprecipitation method and were used to oxidate methane (CH) in presence of oxygen. The CoO-SnO with a molar ratio of Co/(Co+Sn) at 0.75 exhibited the highest catalytic activity among all the CoO-SnO hybrid oxides. Experimental results showed that the catalysts were considerably stable in the CH combustion reaction, and were verified by X-ray photoelectron spectra (XPS). It was found that CoO was the active species, and SnO acted as a support or a promoting component in the CoO-SnO hybrid oxides. The surface area was not a major factor that affected catalytic activity. The hydrogen temperature-programmed reduction (H-TPR) results demonstrated that the interaction between cobalt and tin oxides accelerated the mobility of oxygen species of CoO-SnO, leading to higher catalytic activity.

关键词： Co3O4-SnO2     complete oxidation     methane (CH4)    

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Integration of microbial reductive dehalogenation with persulfate activation and oxidation (Bio-RD-PAO) for complete attenuation of organohalides

《环境科学与工程前沿（英文）》 2022年 第16卷 第2期 doi: 10.1007/s11783-021-1457-8

摘要：

•Bio-RD-PAO can effectively and extensively remove organohalides.

关键词： Bio-RD-PAO     Microbial reductive dehalogenation     Persulfate     Organohalide respiration     Complete attenuation    

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“ALL FREE” — a novel design concept of applying partial oxidation process to vehicle

Ling LIN, Wenshuang LIN, Qingbiao LI, Yao ZHOU,

《化学科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 207-212 doi: 10.1007/s11705-009-0240-3

摘要： With the rapid expansion of the global motor vehicle population, the transportation sector has taken up a growing proportion among all the carbon dioxide emission-related sectors. To contribute to solutions of the carbon dioxide-oriented problem in transportation, this paper proposes the “ALL FREE” concept that applies partial oxidation process instead of the conventional complete oxidation to vehicle engines. In such an engine, the fuels are partially oxidized into corresponding chemical products, which, as a result, enable the process to be theoretically free of CO, while the heat output of the partial oxidation could drive the vehicle. On the other hand, the resulting products are of great value, which could decrease or even counteract the cost of fuels in transportation. In this paper, the thermodynamic and kinetic data (e.g., the heat output and heat release rate) of five selected partial oxidation reactions were calculated at length to demonstrate and exemplify the theoretical feasibility of the “ALL FREE” concept. It turned out that the partial oxidation of -butane to maleic anhydride has the most potential to meet the basic requirements of this concept. To sum up, this design concept is of significant application potential for the reduction of CO emissions in the transportation industry, although there remain many technical challenges.

关键词： oxidation process     CO     complete oxidation     ALL FREE     -butane    

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Research progress and prospects of complete ammonia oxidizing bacteria in wastewater treatment

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1555-2

摘要：

• Comammox bacteria have unique physiological characteristics.

关键词： Complete ammonia oxidizing (comammox) bacteria     Nitrogen cycle     Physiological characteristics     Wastewater treatment    

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Porous silica synthesis out of coal fly ash with no residue generation and complete silicon separation

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1712-2

摘要：

● Both amorphous and crystalline silicon are completely separated from coal fly ash.

关键词： Coal fly ash     Alkali fusion     Micro-/meso-porous Si     Zeolite MCM-48     Crystalline transformation    

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Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology

Wei HUANG, Linmei YU, Wenhui LI, Zhili MA

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 472-475 doi: 10.1007/s11705-010-0525-6

摘要： A new method, named the complete liquid-phase technology, has been applied to prepare catalysts for methanol synthesis. Its main innovative thought lies in preparing slurry catalysts directly from raw solution. Activity tests indicate that the CuZnAl slurry catalyst prepared by the new method can efficiently catalyze conversion of syngas to ethanol in a slurry reactor, while CO conversion reaches 35.9% and ethanol selectivity is more than 20%, with a total alcohol selectivity of more than 87%. No deactivation was found during the 192 h reaction .

关键词： methanol     slurry     ethanol     complete liquid-phase technology     CuZnAl catalyst    

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Existence of complete band gaps in 2D steel-water phononic crystal with square lattice

Cunfu HE, Huanyu ZHAO, Ruiju WEI, Bin WU

《机械工程前沿（英文）》 2010年 第5卷 第4期   页码 450-454 doi: 10.1007/s11465-010-0105-y

摘要： This paper theoretically and experimentally studies the existence of complete band gaps in two-dimensional (2D) phononic crystal consisting of parallel steel rods in water with square lattice. The band structure of phononic crystal is calculated by a plane wave expansion (PWE) method. Based on the well-known ultrasonic immersion transmission technique, the overlapping transmission spectra of acoustic waves, a complete band gap, is experimentally measured along the two high-symmetry directions of the first irreducible Brillouin zone. There is a very good agreement between the experimental result and the range of frequencies of the complete band gap.

关键词： phononic crystal     plane wave expansion (PWE) method     experimental study    

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Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths

Hanbin Zheng, Christine Picard, Serge Ravaine

《化学科学与工程前沿（英文）》 2018年 第12卷 第2期   页码 247-251 doi: 10.1007/s11705-018-1710-2

摘要： Nanostructured metal surfaces have been known to exhibit properties that deviate from that of the bulk material. By simply modifying the texture of a metal surface, various unique optical properties can be observed. In this paper, we present a simple two step electrochemical process combining electrodeposition and anodization to generate black gold surfaces. This process is simple, versatile and up-scalable for the production of large surfaces. The black gold films have remarkable optical behavior as they absorb more than 93% of incident light over the entire visible spectrum and also exhibit no specular reflectance. A careful analysis by scanning electron microscopy reveals that these unique optical properties are due to their randomly rough surface, as they consist in a forest of dendritic microstructures with a nanoscale roughness. This new type of black films can be fabricated to a large variety of substrates, turning them to super absorbers with potential applications in photovoltaic solar cells or highly sensitive detectors and so on.

关键词： nanostructuration     light absorption     coating     gold     electrodeposition     anodization    

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Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-017-0970-2

摘要： Wet air oxidation (WAO) and catalytic wet air oxidation (CWAO) are efficient processes to degrade organic pollutants in water. In this paper, we especially reviewed the WAO and CWAO processes for phenolic compounds degradation. It provides a comprehensive introduction to the CWAO processes that could be beneficial to the scientists entering this field of research. The influence of different reaction parameters, such as temperature, oxygen pressure, pH, stirring speed are analyzed in detail; Homogenous catalysts and heterogeneous catalysts including carbon materials, transitional metal oxides and noble metals are extensively discussed, among which Cu based catalysts and Ru catalysts were shown to be the most active. Three different kinds of the reactor implemented for the CWAO (autoclave, packed bed and membrane reactors) are illustrated and compared. To enhance the degradation efficiency and reduce the cost of the CWAO process, biological degradation can be combined to develop an integrated technology.

关键词： Wet air oxidation     Catalytic wet air oxidation     Phenolic compounds     Heterogeneous catalysts     Mechanism    

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β-Cyclodextrin promoted oxidation of primary amines to nitriles in water

Dongpo SHI, Hongbing JI, Zhong LI

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 196-200 doi: 10.1007/s11705-009-0051-6

摘要： A facile, efficient and substrate-selective oxidation of the primary amines with NaClO as oxidant catalyzed by cyclodextrin ( CD) has been developed in water for the first time, and the behavior of cyclodextrin that catalyzed the primary amines to nitriles in water was investigated. It was found that the primary amines which could form host-guest complexes with cyclodextrin were oxidized to nitriles with excellent yields at ambient temperature. The results show that cyclodextrin worked not only as a solubilizing agent but also as a catalyst in these reactions.

关键词： substrate-selective     amines oxidation     β-cyclodextrin    

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Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1416-4

摘要：

• Solvent-free chitosan oxidation is obtained by rapid mechanochemical reaction.

关键词： Chitosan     High energy ball milling     Mechanochemistry     Oxidation    

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薄煤层刨煤机成套装备关键技术研究

宋秋爽

《中国工程科学》 2011年 第13卷 第11期   页码 33-38

摘要：

针对薄煤层安全、经济开采这一世界性难题，分析我国薄煤层资源分布以及开采技术现状，提出我国刨煤机成套装备系统所存在的技术问题，通过对成套装备关键技术的分析及研究，提出技术解决方法和途径，为刨煤机的自动化工作面提供技术支持。

关键词： 刨煤机成套装备     定向定量推移     异构地质     自适应控制    

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A complete modeling and simulation of DFIG based wind turbine system using fuzzy logic control

Abdelhak DIDA,Djilani BENATTOUS

《能源前沿（英文）》 2016年 第10卷 第2期   页码 143-154 doi: 10.1007/s11708-016-0402-1

摘要： The current paper talks about the variable speed wind turbine generation system (WTGS). So, the WTGS is equipped with a doubly-fed induction generator (DFIG) and two bidirectional converters in the rotor open circuit. A vector control (VC) of the rotor side converter (RSC) offers independent regulation of the stator active and reactive power and the optimal rotational speed tracking in the power maximization operating mode. A VC scheme for the grid-side converter (GSC) allows an independent regulation of the active and reactive power to exchange with the grid and sinusoidal supply currents and keeps the DC-link voltage constant. A fuzzy inference system (FIS) is adopted as an alternative of the conventional proportional and integral (PI) controller to reject some uncertainties or disturbance. The performances have been verified using the Matlab/Simulink software.

关键词： wind turbine generation system (WTGS)     doubly-fed induction generator (DFIG)     maximum power point tracking (MPPT)     vector control (VC)     fuzzy logic controller (FLC)    

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全新产品的创意生成方法分析

师爱芬,谢建华

《中国工程科学》 2002年 第4卷 第11期   页码 89-93

摘要：

从社会和顾客的需要入手，研究了全新产品创意的生成技术及流程图，并分析了“会飞的机器”的创意生成方法和过程，探索了全新产品创意生成的内在规律性。文章首先确定所要构思“产品”的主要特征,再依据物元的蕴含性找到根本特征，进一步寻找具备这些特征的事物和量值。根据事物、特征、量值之间的相依关系按照一定的原理进行组合得出一个系统集合，对这个系统集合进行修整、完善、优化，得出全新产品创意集合。

关键词： 全新产品     创意     物元     物元的蕴含性    

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Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 513-521 doi: 10.1007/s11705-019-1825-0

摘要： Plasma-assisted oxidation of organic compounds is one of the developing technologies for wastewater treatment. Plasmas effectively accelerate degradation processes due to plasma generated reactive species and ultra-violet radiation. Oxidation of benzoic acid in aqueous solutions by the atmospheric pressure glow discharge and underwater diaphragm discharge was studied and monitored by fluorescence and spectrophotometric methods. Discharge type and solution pH affect the formation rates of mono- and dihydroxybenzoic acids. Dihydroxyl derivatives were formed only by glow discharge action. The yields of hydroxyl radical were estimated on the kinetics data for the hydroxylation of benzoic acid. The steps of the hydroxylation processes and further oxidation were described.

关键词： atmospheric pressure glow discharge     underwater diaphragm discharge     oxidation     benzoic acid     hydroxyl radical    

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标题 作者 时间 类型 操作

Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

期刊论文

Integration of microbial reductive dehalogenation with persulfate activation and oxidation (Bio-RD-PAO) for complete attenuation of organohalides

期刊论文

“ALL FREE” — a novel design concept of applying partial oxidation process to vehicle

Ling LIN, Wenshuang LIN, Qingbiao LI, Yao ZHOU,

期刊论文

Research progress and prospects of complete ammonia oxidizing bacteria in wastewater treatment

期刊论文

Porous silica synthesis out of coal fly ash with no residue generation and complete silicon separation

期刊论文

Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technology

Wei HUANG, Linmei YU, Wenhui LI, Zhili MA

期刊论文

Existence of complete band gaps in 2D steel-water phononic crystal with square lattice

Cunfu HE, Huanyu ZHAO, Ruiju WEI, Bin WU

期刊论文

Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths

Hanbin Zheng, Christine Picard, Serge Ravaine

期刊论文

Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

期刊论文

β-Cyclodextrin promoted oxidation of primary amines to nitriles in water

Dongpo SHI, Hongbing JI, Zhong LI

期刊论文

Solvent-free mechanochemical mild oxidation method to enhance adsorption properties of chitosan

期刊论文

薄煤层刨煤机成套装备关键技术研究

宋秋爽

期刊论文

A complete modeling and simulation of DFIG based wind turbine system using fuzzy logic control

Abdelhak DIDA,Djilani BENATTOUS

期刊论文

全新产品的创意生成方法分析

师爱芬,谢建华

期刊论文

Plasma-assisted oxidation of benzoic acid

Anna Khlyustova, Nikolay Sirotkin

期刊论文